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ChemBench

Equilibrium Constant Calculator

The bridge between thermodynamics and equilibrium — how energy determines where a reaction settles.

Equilibrium constant from Gibbs free energy

K is the exponential of minus delta G over RT. A negative delta G gives K greater than 1, meaning products are favoured at equilibrium.

Delta GTemperatureKFavours
-50 kJ/mol298.15 K5.7558 x 10^8Products strongly
-10 kJ/mol298.15 K5.6497 x 10^1Products
-10 kJ/mol500 K1.1085 x 10^1Products, less so when hot
0 kJ/mol298.15 K1.0000Neither
+10 kJ/mol298.15 K1.7700 x 10^-2Reactants
+20 kJ/mol298.15 K3.1330 x 10^-4Reactants strongly

The relationship is exponential, so small energy changes move K enormously: 10 kJ/mol either side of zero spans four orders of magnitude in K.

ΔG° tells you which side wins

A large negative ΔG° gives a large K (products favored), while a large positive ΔG° gives a tiny K (reactants favored). At ΔG° = 0, K = 1 and neither side is favored — the relationship ΔG° = −RT ln K quantifies exactly how strongly a reaction favors products or reactants.

Temperature shifts the equilibrium

Even with the same ΔG°, changing temperature changes K because of the RT factor — this is the mathematical basis of Le Chatelier's principle for temperature changes, and it's why some reactions that are unfavorable at room temperature become favorable at high temperatures.

Frequently asked questions

ΔG° is -30 kJ/mol at 298 K — what is K?

K = exp(-ΔG°/RT) = exp(30000/(8.314×298)) = exp(12.1) ≈ 1.8 × 10⁵. Products are strongly favored.

How is the equilibrium constant related to the Gibbs free energy calculator?

They are two views of the same relationship: ΔG° = -RT ln K. The Gibbs calculator finds ΔG from ΔH and ΔS; this calculator converts that ΔG into K, telling you the product-to-reactant ratio at equilibrium.

Does K change with concentration?

No. K depends only on temperature for a given reaction. Changing concentrations shifts Q (the reaction quotient), driving the system toward or away from equilibrium, but K itself stays fixed at a given temperature.

What does K = 1 mean?

At equilibrium, products and reactants are present in comparable amounts. K >> 1 means products dominate; K << 1 means reactants dominate. K = 1 is the thermodynamic tipping point where ΔG° = 0.

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Last updated: September 7, 2026