ChemBench
Charles's Law Calculator
Heat it up, it expands.
Charles's law: volume against temperature at fixed pressure
V1/T1 = V2/T2, with temperature in kelvin. Double the absolute temperature and the volume doubles.
| Initial volume | Initial temperature | New temperature | New volume |
|---|---|---|---|
| 1 L | 273.15 K (0 C) | 546.30 K | 2.0000 L |
| 1 L | 273.15 K (0 C) | 298.15 K (25 C) | 1.0915 L |
| 2 L | 300 K | 600 K | 4.0000 L |
| 5 L | 273.15 K (0 C) | 373.15 K (100 C) | 6.8305 L |
| 10 L | 298.15 K (25 C) | 273.15 K (0 C) | 9.1615 L |
Kelvin is essential here. Going from 0 C to 25 C expands a gas by 9%, not by an infinite amount, because the ratio is 298.15 to 273.15, not 25 to 0.
Volume and temperature rise together
At constant pressure, a gas's volume is directly proportional to its absolute temperature (in Kelvin) — double the temperature and the volume doubles too.
Why a hot air balloon rises
Heating the air inside a balloon expands its volume (Charles's Law in action), making that air less dense than the surrounding cooler air and generating buoyant lift.
Frequently asked questions
A balloon holds 3.0 L of air at 20°C — what volume will it be at 80°C?
Convert to Kelvin: T1 = 293 K, T2 = 353 K. V2 = V1 × T2/T1 = 3.0 × 353/293 = 3.61 L.
Why do I need to use Kelvin and not Celsius?
Charles's law requires an absolute temperature scale. At 0°C the formula would predict zero volume, which is physically wrong. Kelvin starts at absolute zero, so the direct proportionality V/T = constant holds correctly.
How is Charles's law different from Gay-Lussac's law?
Charles's law relates volume and temperature at constant pressure. Gay-Lussac's law relates pressure and temperature at constant volume. Both are special cases of the ideal gas law — use Gay-Lussac's calculator for sealed rigid containers.
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OpenLast updated: September 7, 2026